Tauc plot
A Tauc plot[1] is used to determine the optical bandgap, or Tauc gap, in semiconductors.[2] The Tauc gap is often used to characterize practical optical properties of amorphous materials.
Jan Tauc (/taʊts/) showed that the optical absorption spectrum of amorphous germanium resembles the spectrum of the indirect transitions in crystalline germanium (plus a tail due to localized states at lower energies), and proposed an extrapolation to find the optical gap of these crystalline-like states.[3] Typically, a Tauc plot shows the quantity hν (the energy of the light) on the abscissa and the quantity (αhν)1/r on the ordinate, where α is the absorption coefficient of the material. The value of the exponent r denotes the nature of the transition:[4]
- r = 1/2 for direct allowed transitions
- r = 3/2 for direct forbidden transitions.
- r = 2 for indirect allowed transitions
- r = 3 for indirect forbidden transitions
The resulting plot has a distinct linear regime which denotes the onset of absorption. Thus, extrapolating this linear region to the abscissa yields the energy of the optical band gap of the material.
References
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