Xenic acid

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Xenic acid
Structural formula
Identifiers
ChemSpider 10466143 N
Jmol 3D model Interactive image
  • InChI=1S/H2O4Xe/c1-5(2,3)4/h1-2H N
    Key: HRLLZBGOCZURJC-UHFFFAOYSA-N N
  • InChI=1/H2O4Xe/c1-5(2,3)4/h1-2H
    Key: HRLLZBGOCZURJC-UHFFFAOYAW
  • O[Xe](=O)(=O)O
Properties
H2XeO4
Molar mass 197.31 g/mol
Vapor pressure {{{value}}}
Related compounds
Related compounds
Perxenic acid
Xenon trioxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Xenic acid is a noble gas compound formed by the dissolution of xenon trioxide in water. Its chemical formula is H2XeO4. It is a very powerful oxidizing agent, and its decomposition is dangerous as it liberates a large amount of gaseous products: xenon, oxygen, and ozone.

Its existence was hypothesized by Linus Pauling in 1933.[1] Xenic acid has been used as an oxidizing agent in organic chemistry.

Salts of xenic acid are called xenates, containing the HXeO
4
anion. They tend to disproportionate into xenon gas and perxenates:[2]

2 HXeO
4
+ 2 OH
XeO4−
6
+ Xe + O
2
+ 2 H
2
O

The energy given off is sufficient to form ozone from diatomic oxygen:

3 O
2
(g) → 2 O
3
(g)

Salts containing the completely deprotonated anion XeO2−
4
are presently unknown.[2]

References

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External links

  • Xenic Acid Reactions with vic-Diols[1]

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